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Consider the following Bronsted-Lowry acid-base reaction: C6H5NH2 + HCOOH→C6H5NH3+ + HCOO - Which of the following is a conjugate acid-base pair?


A) C6H5NH2 and HCO2H
B) HCOOH and C6H5NH3+
C) HCOO - and C6H5NH2
D) C6H5NH3+ and C6H5NH2
E) C6H5NH3+ and HCOO -

F) None of the above
G) B) and C)

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D

What is the acid ionization constant , K a, for Chlorous acid, HClO2, if a 0.25 M aqueous solution of chlorous acid has a pH equal to 1.33? You may want to complete the ICE table before getting started. HClO2 H3O+ ClO21 - Initial Change @ equilibrium


A) K a = 2.2×10 - 3
B) K a = 7.4×10 - 3
C) K a = 8.8×10 - 3
D) K a = 1.1×10 - 2
E) K a = 4.7×10 - 2

F) None of the above
G) B) and D)

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In the reaction: N₂H4 (aq) + H₂ O In the reaction: N₂H<sub>4</sub> (aq)  + H₂ O   N₂H<sub>5</sub> + (aq)  + OH - (aq)  A)  N<sub>2</sub>H<sub>4</sub> and N<sub>2</sub>H<sub>5</sub><sup>+</sup> act as acids. B)  H<sub>2</sub>O and N<sub>2</sub>H<sub>5</sub><sup>+</sup> act as acids. C)  N<sub>2</sub>H<sub>5</sub><sup>+</sup> and OH<sup> - </sup> act as acids. D)  only OH<sup> - </sup> acts as a base. E)  none of these. N₂H5 + (aq) + OH - (aq)


A) N2H4 and N2H5+ act as acids.
B) H2O and N2H5+ act as acids.
C) N2H5+ and OH - act as acids.
D) only OH - acts as a base.
E) none of these.

F) All of the above
G) C) and D)

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Regarding acid strength, which of the following is not correctly assigned?


A) (weaker acid) NH3 < H2O (stronger acid)
B) (weaker acid) HSO31 - < H2SO3 (stronger acid)
C) (weaker acid) HBrO2 < HBrO3 (stronger acid)
D) (weaker acid) HBr < HI (stronger acid)
E) (weaker acid) HClO3 < HIO3 (stronger acid)

F) D) and E)
G) A) and C)

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E

Which aqueous solution(s) below is(are) considered basic ? I. A solution with a pH = 6 II. A solution with [OH - ] = 1×10 - 7 III. A solution with [H3O+] = 1×10 - 9


A) I only
B) II only
C) III only
D) I and II
E) I and III

F) None of the above
G) A) and E)

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What is the pOH of a 1.0×10 - 4 M solution of HI?


A) 10.00
B) 4.00
C) 18.00
D) - 4.00
E) 2.00

F) A) and D)
G) B) and C)

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If the reaction below proceeds, which of the following is true? NH3 + C2H5OH→NH2 - + C2H5OH2+


A) C2H5OH is an acid.
B) NH2 - is the conjugate base of NH3.
C) NH3 is a base.
D) C2H5OH2+ is a base.
E) none of these

F) B) and C)
G) C) and D)

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K b for ammonia is 1.8×10 - 5. Calculate K a for the ammonium ion.


A) 5.6×104
B) 4.2×10 - 3
C) 1.8×10 - 5
D) 1.0×10 - 7
E) 5.6×10 - 10

F) All of the above
G) A) and E)

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Consider adding NaClO4 to a basic solution. Which statement below is true?


A) NaClO4 is an acidic salt and the pH of the resulting solution rises.
B) NaClO4 is an acidic salt and the pH of the resulting solution lowers.
C) NaClO4 is a basic salt and the pH of the resulting solution rises.
D) NaClO4 is a basic salt and the pH of the resulting solution lowers.
E) NaClO4 is a neutral salt and the pH of the resulting solution does not change.

F) A) and B)
G) B) and D)

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What is the pH of an aqueous 0.036 M NaF solution? K a(HF) = 6.8×10 - 4


A) pH = 1.44
B) pH = 2.31
C) pH = 6.14
D) pH = 7.86
E) pH = 11.69

F) A) and B)
G) D) and E)

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At 37 ° C the autoionization constant of water is K w = 2.4×10 - 14. What is the pH of pure water at 37 ° C?


A) 6.81
B) 7.00
C) 7.19
D) 2.39
E) 11.61

F) A) and B)
G) A) and C)

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What is the pH of a 0.025 M solution of HSCN ( K a = 4.0×10 - 6) ?


A) 1.60
B) 3.50
C) 4.21
D) 5.39
E) 7.00

F) All of the above
G) None of the above

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Aniline, C6 H5 NH₂ , is commonly used as a precursor for making dyes. Aniline is a base when dissolved in water. It ionizes as shown below. What is the base ionization constant, K b , of aniline if an aqueous 0.20 M C6 H5 NH₂ solution has a pOH value equal tO5 .05? C6 H5 NH₂ + H₂ O Aniline, C<sub>6</sub> H<sub>5</sub> NH₂ , is commonly used as a precursor for making dyes. Aniline is a base when dissolved in water. It ionizes as shown below. What is the base ionization constant, K b , of aniline if an aqueous 0.20 M C<sub>6</sub> H<sub>5</sub> NH₂ solution has a pOH value equal tO<sub>5</sub> .05? C<sub>6</sub> H<sub>5</sub> NH₂ + H₂ O   C<sub>6</sub> H<sub>5</sub> NH₃+ + OH - A)  K <sub>b</sub> = 6.3×10<sup> - 18</sup> B)  K <sub>b</sub> = 4.0×10<sup> - 10</sup> C)  K <sub>b</sub> = 4.5×10<sup> - 5</sup> D)  K <sub>b</sub> = 1.5×10<sup> - 2</sup> E)  K <sub>b</sub> = 6.3×10<sup>10</sup> C6 H5 NH₃+ + OH -


A) K b = 6.3×10 - 18
B) K b = 4.0×10 - 10
C) K b = 4.5×10 - 5
D) K b = 1.5×10 - 2
E) K b = 6.3×1010

F) B) and C)
G) A) and C)

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50 mL of 0.50 M NaOH is added to enough water to make 1.0 liter of solution. Calculate the pH.


A) 0.3
B) 1.6
C) 12.4
D) 12.7
E) 13.7

F) A) and B)
G) C) and E)

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An acid HB+ has a K a of 1.0×10 - 9. What is the p K b of the base B?


A) 9.0
B) 7.0
C) 5.0
D) 1.0×10 - 5
E) 1.0×10 - 9

F) D) and E)
G) B) and C)

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Which anionic base listed below would be the strongest given the corresponding acid ionization constants for their conjugate acids?


A) F - ; K a(HF) = 6.8×10 - 4
B) CH3COO - ; K a(CH3COOH) = 1.8×10 - 5
C) IO31 - ; K a(HIO3) = 1.6×10 - 1
D) NO21 - ; K a(HNO2) = 7.1×10 - 4

E) B) and D)
F) A) and D)

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A nitric acid (HNO3) solution is 16.2 M. Which of the following is correct?


A) pH = 1.21
B) pH = 2.78
C) pOH = 15.21
D) [OH - ] = 1.62×1015
E) must know K a

F) A) and E)
G) All of the above

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After completing the following unfinished table, what is the order of increasing base strength ? Base K b p K b Fluoride ion, F - 1.5×10 - 11 Ammonia, NH3 4.75 Acetate ion, CH3COO - 5.7×10 - 10


A) (weakest) Fluoride ion < Ammonia < Acetate ion (strongest)
B) (weakest) Fluoride ion < Acetate ion < Ammonia (strongest)
C) (weakest) Ammonia < Fluoride ion < Acetate ion (strongest)
D) (weakest) Acetate ion < Ammonia < Fluoride ion (strongest)
E) (weakest) Acetate ion < Fluoride ion < Ammonia (strongest)

F) A) and C)
G) C) and D)

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A 0.250 M aqueous solution of p -toluic acid has a pH of 2.49. What is K a for this weak acid?


A) 4.2×10 - 5
B) 3.2×10 - 3
C) 1.3×10 - 2
D) 2.4×10 - 10
E) 1.0×10 - 5

F) D) and E)
G) B) and D)

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When 20.0 grams of a water soluble salt dissolves in 1.0 L of pure water the pH was found to be less than seven. Which of the following statements about the salt is most probable?


A) The salt contained the conjugate acid of a strong base.
B) The salt contained the conjugate base of a strong acid.
C) The salt contained the conjugate base of a weak acid.
D) The salt contained the conjugate acid of a weak base.
E) The salt was impure and contained some NH4Cl.

F) B) and E)
G) A) and E)

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D

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